CombiEIS Potentiostatic

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CombiEIS Potentiostatic

Description

The CombiEIS Potentiostatic technique is used to characterize an electrochemical interface which is held at a fixed potential. A small-amplitude AC-voltage excitation is applied to an electrochemical cell. The phase-sensitive AC response of the interface is measured as the frequency of the excitation signal is varied. The CombiEIS Potentiostatic technique combines the time-saving advantages of the OptiEIS Potentiostatic technique for low-frequency EIS with the high-frequency speed of standard single-sine EIS. With CombiEIS scripts it is possible to obtain impedance spectra over the full instrument frequency limits, while saving a significant amount of time on the low-frequency portion of the spectra.

 

EIS is a particularly powerful tool for the study of coated-metal corrosion. It is also useful in almost every other area of electrochemistry, including research in batteries, electrode kinetics, and industrial electrolysis. The output of an EIS experiment is a complex impedance spectrum. The term complex is used in its mathematical sense: containing both real and imaginary terms. An EIS spectrum is usually graphed as either a Bode plot (impedance magnitude and phase plotted versus frequency) or a Nyquist plot (imaginary impedance plotted versus real impedance). Analysis of the impedance spectrum can give you the following information:

 

Polarization resistance

Double-layer capacitance

Solution resistance

Coating-defect parameters

Mechanistic and kinetic information